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are captured properly by the TVM simulations. In abstract, the robust northerly synoptic wind on 12 and 13 September carried pollution over the ocean during the night time and early morning, the place it stayed through the day as a result of sea breezes were not robust enough to penetrate inland. These phenomena are Top collection i stand for the flag and i kneel before God american flag all over print flag reproduced well by the model. For the dynamical calculations, every of the three day by day simulations was carried out separately. The simulations start at 2200 LT, with horizontally homogeneus preliminary situations based mostly on the vertical soundings of the Hellenikon Airport, and last for 26 h. These soundings show a free tropospheric wind from the northwest with variable velocity from 2 m s−1 to 8 m s−1 (12 and thirteen September; see Table 1). The geostrophic wind, atmospheric stability, and boundary circumstances are fastened equal to the initial values and usually are not changed through the simulation interval. The first 2 h of the simulation are considered to be an initialization period, and the outcomes are analyzed starting from 0000 LT. The modeling domain (Fig. 1) is 72 km × 72 km with a grid spacing of 2 km × 2 km that enables the town of Athens, the Saronic Gulf, Aigina Island , Mt. Parnitha , Pendeli, and the Hymettus hills to be distinguished clearly. Transport is computed by a 3rd-order constructive particular advection scheme , known as the piecewise parabolic methodology, corrected for multidimensional applications . A 500 m2 s−1 constant horizontal diffusion coefficient is used within the present calculations, based on the outcomes of different warmth-island and mountain-wave 2D instances . Analytical functions of Louis are used to compute wind velocities and temperature within the surface layer, and fluxes are computed with a soil–vegetation–ambiance switch model . This module solves prognostic equations for temperature and humidity within the soil using four computational levels and accounts for the presence of vegetation. Pollutant transport makes use of the identical advection scheme as is used in the dynamical module, and turbulent transport is solved in the vertical by use of the dynamic diffusion coefficients. three. A specific humidity equation (on this mannequin version, air is assumed to be unsaturated; there isn’t any condensation and no latent heating). A cellular differential absorption lidar system developed at the Swiss Federal Institute of Technology was used within the MEDCAPHOT–TRACE experiment to measure 3D ozone concentrations over the site of Demokritos within the northeastern part of GAA (location 31 in Fig. three). A detailed description of system efficiency is

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